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Non-Ionic Flocculant Polyacrylamide: Basic Properties and Synthesis Methods

With the advancement of industrialization, wastewater treatment has become a significant issue in the field of environmental protection. Non-ionic flocculant polyacrylamide (NPAM) has become a key material in industrial wastewater treatment due to its unique properties. This article will explore the basic properties and synthesis methods of non-ionic flocculant polyacrylamide to help understand its application value in wastewater treatment.


Basic Properties of Non-ionic Flocculant Polyacrylamide


Water Solubility and Hydrophilicity


Non-ionic flocculant polyacrylamide is a polymer with a molecular chain containing polar groups such as amide groups. These polar groups give non-ionic flocculant polyacrylamide excellent water solubility and hydrophilicity, allowing it to dissolve in water in any proportion and form a uniform solution. This characteristic makes non-ionic flocculant polyacrylamide highly effective in wastewater treatment, significantly improving the clarity and filtration of water.


Electrolyte Tolerance


Non-ionic flocculant polyacrylamide has a high tolerance to electrolytes, such as ammonium chloride and sodium sulfate, which have minimal impact on its performance. This tolerance allows it to work stably under various environmental conditions, widely applied in various industrial wastewater treatments.


Physical Properties


Non-ionic flocculant polyacrylamide's physical properties are primarily reflected in its ability to handle suspended particles in water. Due to the flexibility of its molecular chain and the presence of polar groups, it can effectively adsorb suspended particles in water, promoting aggregation into larger flocs through charge neutralization or bridging action. This performance not only accelerates the sedimentation of particles in suspension but also enhances the clarity and filtration of the solution.


Chemical Properties


Non-ionic flocculant polyacrylamide's chemical properties are mainly reflected in the amide groups on its molecular chain. These active side groups can undergo various chemical reactions, although these reactions are often incomplete due to the neighboring group effect. However, through modification or composite treatment, the performance of non-ionic flocculant polyacrylamide can be further improved to meet the needs of different applications.


Synthesis Methods of Non-ionic Flocculant Polyacrylamide


Free Radical Polymerization


Free radical polymerization is one of the traditional methods for synthesizing non-ionic flocculant polyacrylamide. This method uses acrylamide monomers as raw materials, and through the action of initiators, a free radical polymerization reaction occurs to produce non-ionic flocculant polyacrylamide. The free radical polymerization method is simple, with mild reaction conditions, but the product often has a broad molecular weight distribution, usually requiring subsequent processing to improve its performance.


Microbial Nitrilase Catalysis Production


In recent years, microbial nitrilase catalysis production technology has gained attention as a new synthesis method. This technology uses nitrilase produced by microorganisms to convert acrylonitrile into acrylamide monomers, which are then polymerized to form non-ionic flocculant polyacrylamide. This method has the advantages of mild reaction conditions, high conversion rate, and no by-products, while the produced non-ionic flocculant polyacrylamide has high purity and does not contain impurities such as metal ions.

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